Microelectronic structure by selective deposition

ABSTRACT

A finFET structure includes a semiconductor fin located over a substrate. A gate electrode is located traversing the semiconductor fin. The gate electrode has a spacer layer located adjoining a sidewall thereof. The spacer layer does not cover completely a sidewall of the semiconductor fin. The gate electrode and the spacer layer may be formed using a vapor deposition method that provides for selective deposition upon a sidewall of a mandrel layer but not upon an adjoining surface of the substrate so that the spacer layer does not cover completely the sidewall of the semiconductor fin. Other microelectronic structures may be fabricated using the lateral growth methodology.

RELATED APPLICATION

This application is a continuation of U.S. patent application Ser. No.11/307,294, filed Jan. 31, 2006.

BACKGROUND

1. Field of the Invention

The invention relates generally to microelectronic structures. Moreparticularly, the invention relates to selective methods for formingmicroelectronic structures.

2. Description of the Related Art

As semiconductor device technology continues to advance, a need existsfor semiconductor devices that provide enhanced performance withinlimited semiconductor substrate area. A class of semiconductor devicesthat has recently evolved to meet the foregoing performance and densityneeds is known as finFET devices.

finFET devices are semiconductor devices that comprise a semiconductorfin located edgewise upon a substrate. A pair of gate dielectric layersis typically located one each upon both major vertical surfaces, andoptionally also contiguously upon a top surface, of the semiconductorfin. An inverted U shaped gate electrode often straddles a centralsection of the semiconductor fin and covers the gate dielectric layers.In other instances, a portion of a gate electrode is not located atopthe semiconductor fin, and thus a pair of gate electrodes is restrictedto the sidewalls of the semiconductor fin. End portions of thesemiconductor fin uncovered by the gate electrode are typically subjectto ion implantation while using the gate electrode or other maskinglayer as a mask, to thus provide source/drain regions within thesemiconductor fin that are separated by a channel region located beneathor covered by the gate electrode(s) within the semiconductor fin.

finFET devices provide several advantages in comparison withconventional planar field effect transistor devices. In particular,since finFET devices are vertical channel devices, they may be scaledeffectively in the vertical direction, while not using any additionalsemiconductor substrate area. Thus, finFET devices offer an opportunityfor enhanced semiconductor device performance absent an increase inaerial dimensions.

finFET devices clearly provide a novel approach for increasingsemiconductor device performance. However, finFET devices are notentirely without difficulty. finFET fabrication generally involvesforming a gate electrode having a considerable thickness upon asemiconductor fin that might also be readily scaled to a considerableheight. The topography induced by the crossing of such a fin structurewith such a gate structure may, under certain circumstances, providefabrication difficulties.

A need thus exists for providing finFET structures, and methods forfabrication thereof that are readily manufacturable.

SUMMARY OF THE INVENTION

The invention provides a finFET structure, a method for fabricating thefinFET structure and a method for fabricating a microelectronicstructure that need not necessarily be a finFET structure. The structureand the first method may use a laterally selective deposition methodthat, in turn, uses a vertical sidewall activated mandrel layer locatedupon a horizontal surface passivated (i.e., inactivated) substratewithin the context of finFET gate structure fabrication. The secondmethod uses the vertical sidewall activated mandrel layer laterallyselective deposition aspects of the invention, but not necessarilywithin the context of finFET structure fabrication.

A semiconductor structure in accordance with the invention comprises asemiconductor fin located over a substrate. The semiconductor structurealso comprises a gate electrode located traversing the semiconductorfin. The gate electrode has a spacer layer located adjacent a sidewallthereof. The spacer layer does not cover completely a sidewall of thesemiconductor fin remote from the gate electrode.

A related method for fabricating a semiconductor structure in accordancewith the invention provides for forming a semiconductor fin over asubstrate. The method also provides for forming a gate electrode overthe substrate and traversing a portion of the semiconductor fin.Finally, the method also provides for forming a spacer layer over thesubstrate and also traversing a portion of the semiconductor fin. Withinthe method, the spacer layer is adjacent a sidewall of the gateelectrode, but the spacer layer does not cover completely a sidewall ofthe semiconductor fin remote from the gate electrode.

Finally, a second method for forming a microelectronic structure inaccordance with the invention provides for forming a mandrel layer overa substrate. A sidewall of the mandrel layer is activated with respectto vapor deposition of a material layer upon the sidewall of the mandrellayer. A surface of the substrate is passivated with respect to vapordeposition of the material layer upon the surface of the substrate. Themethod also provides for vapor depositing and selectively laterallygrowing the material layer upon the sidewall of the mandrel layer butnot upon the surface of the substrate.

BRIEF DESCRIPTION OF THE DRAWINGS

The objects, features and advantages of the invention are understoodwithin the context of the Description of the Preferred Embodiment, asset forth below. The Description of the Preferred Embodiment isunderstood within the context of the accompanying drawings, which form amaterial part of this disclosure, wherein:

FIG. 1 to FIG. 18 show a series of schematic cross-sectional andplan-view diagrams illustrating the results of progressive stages infabricating a finFET structure in accordance with a preferred embodimentof the invention.

DESCRIPTION OF THE PREFERRED EMBODIMENT

The invention provides a finFET structure, a method for fabricating thefinFET structure and a method for fabricating a microelectronicstructure that need not necessarily be a finFET structure. The structureand the first method may use a laterally selective deposition methodthat, in turn, uses a vertical sidewall activated mandrel layer locatedupon a horizontal surface passivated (i.e., inactivated) substratewithin the context of finFET gate fabrication. The second method usesthe sidewall selective lateral deposition aspects of the invention, butnot necessarily within the context of finFET fabrication.

FIG. 1 to FIG. 18 show a series of schematic cross-sectional andplan-view diagrams illustrating the results of progressive stages infabricating a finFET structure in accordance with a preferred embodimentof the invention.

FIG. 1 and FIG. 2 show, respectively, a schematic cross-sectionaldiagram and a schematic plan-view diagram of the finFET structure at anearly stage in its fabrication. FIG. 1 in particular shows a substrate10. A dielectric layer 12 is located upon the substrate 10. Asemiconductor fin 14 is located upon the dielectric layer 12. Apatterned hard mask layer 16 is located upon the semiconductor fin 14.Finally, a pair of gate dielectric layers 18 a and 18 b is located upona pair of opposite sidewalls of the semiconductor fin 14.

Each of the foregoing substrate 10 and layers may comprise materials andhave dimensions that are conventional in the semiconductor fabricationart. Each of the foregoing substrate 10 and layers may also be formedusing methods that are conventional in the semiconductor fabricationart.

The substrate 10 typically comprises a semiconductor material, althoughthe invention is not so limited. The substrate 10 may alternativelycomprise a conductor material or a dielectric material. Non-limitingexamples of semiconductor materials which may be used as the substrate10 include, silicon, germanium, silicon-germanium alloy, siliconcarbide, silicon-germanium carbide and compound (i.e., II-VI and III-V)semiconductor materials. Non-limiting examples of compound semiconductormaterials include gallium arsenide, indium arsenide and indium phosphidesemiconductor materials. Typically, the substrate 10 comprises a siliconor silicon-germanium alloy (e.g., typically from about 25 to about 35atomic percent germanium) semiconductor material having a thickness fromabout 1 to about 3 mils.

The dielectric layer 12 serves as a substrate layer for a finFETstructure fabricated in accordance with the instant embodiment. Thedielectric layer 12 may comprise any of several dielectric materials.Non-limiting examples include oxides, nitrides and oxynitrides,typically of silicon, but oxides, nitrides and oxynitrides of otherelements are also not excluded. The dielectric layer 12 may be formedusing any of several methods. Non-limiting examples include thermal orplasma oxidation methods, thermal or plasma nitridation methods,chemical vapor deposition methods and physical vapor deposition methods.Typically, the dielectric layer 12 comprises a silicon orsilicon-germanium alloy oxide material that has a thickness from about200 to about 1000 angstroms.

The semiconductor fin 14 also comprises a semiconductor material. Thesemiconductor material may be selected from the same group ofsemiconductor materials from which is comprised the substrate 10, whenthe substrate 10 comprises a semiconductor material. The substrate 10and the semiconductor fin 14 may comprise the same or differentsemiconductor materials with respect to chemical composition, dopantconcentration and crystallographic orientation. Typically, thesemiconductor fin 14 has a linewidth from about 500 to about 700angstroms and a height from about 1000 to about 5000 angstroms.Typically the semiconductor fin 14 comprises a silicon orsilicon-germanium alloy semiconductor material.

The patterned hard mask layer 16 may comprise a hard mask material thatis otherwise generally conventional in the semiconductor fabricationart. Oxide, nitride and oxynitride hard mask materials are common, butby no means limiting. The patterned hard mask layer 16 may, in someinstances, be formed using methods and materials analogous, equivalentor identical to the methods and materials used for forming thedielectric layer 12. Preferably, the patterned hard mask layer 16comprises a silicon nitride hard mask material that has a thickness fromabout 200 to about 500 angstroms.

The pair of gate dielectric layers 18 a and 18 b may comprise agenerally conventional dielectric material having a dielectric constantfrom about 4 to about 20, measured in vacuum. Such a dielectric materialmay comprise a silicon oxide, a silicon nitride or a silicon oxynitridedielectric material. Alternatively, the pair of gate dielectric layers18 a and 18 b may comprise a generally higher dielectric constantdielectric material having a dielectric constant from about 20 to atleast about 100. Such higher dielectric constant dielectric materialsinclude, but are not limited to: hafnium oxides, hafnium silicates,titanium oxides, barium strontium titanates (BSTs) and lead zirconatetitanates (PZTs). The gate dielectric layers 18 a and 18 b may be formedusing methods that are appropriate to their materials of composition.The methods may include, but are not limited to: thermal oxidation ornitridation methods, plasma oxidation or nitridation methods, chemicalvapor deposition methods and physical vapor deposition methods.Typically, each of the pair of gate dielectric layers 18 a and 18 bcomprises a silicon oxide material having a thickness from about 20 toabout 70 angstroms. Preferably, the silicon oxide material is formedusing a thermal oxidation method.

When the substrate 10 comprises a semiconductor material, thesemiconductor structure of FIG. 1 and FIG. 2 may be fabricated by usinga semiconductor-on-insulator substrate. A semiconductor-on-insulatorsubstrate comprises: (1) a semiconductor substrate (i.e., the substrate10); (2) a buried dielectric layer located upon the semiconductorsubstrate (i.e., the dielectric layer 12); and (3) a surfacesemiconductor layer (i.e., from which is formed the semiconductor fin14) located upon the buried dielectric layer. A blanket hard mask layeris then located upon the surface semiconductor layer. A patternedphotoresist layer is located upon the blanket hard mask layer, and theblanket hard mask layer is patterned to form the patterned hard masklayer 16. At least the patterned hard mask layer 16 is then used forforming the semiconductor fin 14 from the surface semiconductor layerwithin the semiconductor-on-insulator substrate. Once the semiconductorfin 14 is patterned from the surface semiconductor layer while using thepatterned hard mask layer as an etch mask layer, the semiconductor fin14 may be thermally oxidized to form the pair of gate dielectric layers18 a and 18 b.

Semiconductor-on-insulator substrates may be fabricated using any ofseveral methods. Non-limiting examples include lamination methods, layertransfer methods and separation by implantation of oxygen (SIMOX)methods. The instant embodiment is not limited to use of onlysemiconductor-on-insulator substrates. Rather the embodiment alsocontemplates use of at least bulk semiconductor substrates and bulkdielectric substrates (i.e., a dielectric substrate consisting of only adielectric material, and absent a conductor material or a semiconductormaterial) when fabricating thereupon or thereover semiconductorstructures, non-limiting examples of which include finFET structures(i.e., finFET gate structures).

FIG. 3 and FIG. 4 show a schematic cross-sectional and schematicplan-view diagram illustrating the results of further processing of thesemiconductor structure whose schematic cross-sectional and plan-viewdiagrams are illustrated in FIG. 1 and FIG. 2.

FIG. 3 shows a patterned capping layer 22 located aligned upon apatterned mandrel layer 20. In turn, the patterned mandrel layer 20encapsulates a portion of the semiconductor fin 14, the patterned hardmask layer 16 and the pair of gate dielectric layers 18 a and 18 b. FIG.4 further shows that the patterned capping layer 22 traverses a centralportion of the patterned hard mask layer 16, and thus also a centralportion of the semiconductor fin 14 aligned therebeneath. Sidewall andtop portions of the patterned capping layer 22 are exposed, as aresidewall portions of the patterned mandrel layer 20 and top portions ofthe dielectric layer 12.

The patterned mandrel layer 20 comprises a mandrel material that iseither: (1) intrinsically active with respect to a vapor depositionmethod for forming a particular material layer upon a sidewall of thepatterned mandrel layer 20; or alternatively (2) readily activatablewith respect to the vapor deposition method for forming the particularmaterial layer upon the sidewall of the patterned mandrel layer 20.

As a general rule and within the context of the instant embodiment andthe invention, a mandrel material is either: (1) intrinsically “active”;or (2) otherwise “activatable,” if it either: (1) intrinsicallycomprises; or (2) may be chemically modified to comprise, surfacechemical functionality that provides for enhanced deposition of theparticular material layer upon the active or activatable sidewallsurface of the patterned mandrel layer 20. Enhanced deposition istypically realized with respect to active or activatable surfaces thatcomprise an organic acid, hydroxyl or amine functionality. Aminefunctionality is often quite desirable. Retarded deposition (i.e,“inactive” surface or “passive” surface) is typically realized withrespect to passive or passivatable surfaces that comprise chemicallynon-functional organic (i.e., typically alkyl) surfaces. In accordancewith the foregoing options, the patterned mandrel layer 20 will thustypically have a desirable generally wettable surface (i.e., organicacid, hydroxyl or amine functionality that provides a sessile water dropcontact angle of less than about 30 degrees). For comparison, anon-wettable surface (i.e., non-functional organic such as alkylproviding a surface having a sessile water drop contact angle of greaterthan about 90 degrees) will typically yield a retarded or inhibiteddeposition of a particular material layer thereupon while using a vapordeposition method.

Thus, the patterned mandrel layer 20 preferably comprises a mandrelmaterial that is either: (1) intrinsically chemically functional toprovide a wettable surface with respect to a vapor deposition method; orin the alternative (2) readily functionizable to provide a wettablesurface with respect to the vapor deposition method. Again, aminefunctionality is a particularly preferred chemical functionality forproviding the wettable surface.

While by no means a limitation of the invention, a patterned mandrellayer 20 comprising or consisting of an anhydride material, and inparticular a maleic anhydride material (i.e., intended as a polymerizedmaleic anhydride material, a co-polymer of a maleic anhydride material,or in general a polymer containing an anhydride functionality or asimilar reactive group functionality) may be advantageously used withinthe context of the invention. In accordance with further disclosurebelow, the maleic anhydride material may be efficiently treated with amulti-functional amine to provide the wettable amine rich surface thatis advantageously desirable within the context of the instantembodiment. The maleic anhydride material may be deposited using methodsthat are conventional in the semiconductor fabrication art. Such methodsmay include, but are not limited to: thermal vapor deposition (i.e.,evaporation) methods, plasma deposition methods, spin coating methodsand solvent casting methods. Preferably, the patterned mandrel layer 20has a thickness from about 3000 to about 7000 angstroms, whichcompletely encapsulates the semiconductor fin 14 and the patterned hardmask layer 16. Nonetheless, the invention is not so limited, and lesserthicknesses for the patterned mandrel layer 20 may be used. Also, thepatterned mandrel layer 20 has a linewidth from about 0.1 to about 0.3microns.

As an alternative, a patterned mandrel layer comprising or consisting ofa polymerized hydroxysiloxane material may also be used. In addition,oxygen plasmas, oxidizing acids (i.e., sulfuric acid and nitric acid)and peroxides such as hydrogen peroxide may be used to provide oxidizedactivated mandrel layer surfaces. Finally, introduction of metaladditives into mandrel materials may also assist in providing activatedsurfaces for vapor depositing material layers thereupon.

The patterned capping layer 22 may comprise capping materials analogous,equivalent or identical to the hard mask materials from which arecomprised the patterned hard mask layer 16. Silicon oxides, siliconnitrides and silicon oxynitrides are common, but for reasons that aredisclosed in further detail below silicon nitride materials aredesirable for both the patterned hard mask layer 16 and the patternedcapping layer 22. Typically, the patterned capping layer 22 has athickness from about 100 to about 500 angstroms. Typically, thepatterned capping layer 22 is formed using a chemical vapor depositionor physical vapor deposition method at a temperature sufficiently low sothat there is no detrimental effect upon the patterned mandrel layer 20.

To form the semiconductor structure whose schematic cross-sectional andplan-view diagrams are illustrated in FIG. 3 and FIG. 4 from thesemiconductor structure whose schematic cross-sectional and plan-viewdiagrams are illustrated in FIG. 1 and FIG. 2, a blanket mandrelmaterial layer is first located upon the semiconductor structure whoseschematic cross-sectional and plan-view diagrams are illustrated in FIG.1 and FIG. 2. A blanket capping layer is then located upon the blanketmandrel layer. A patterned photoresist layer is then located upon theblanket capping layer. The blanket capping layer is patterned to formthe patterned capping layer 22 while using the patterned photoresistlayer as an etch mask. At least the patterned capping layer 22 is thenused as an etch mask for forming the patterned mandrel layer 20 from theblanket mandrel layer. Often, the patterned photoresist layer may besimultaneously stripped from the patterned capping layer 22 when anoxygen containing plasma is used for etching the blanket mandrel layerwhen forming the patterned mandrel layer 20. The foregoing processsequence is exemplary only, and by no means does the process sequencelimit either the instant embodiment or the invention.

FIG. 5 and FIG. 6 show a pair of schematic cross-sectional and plan-viewdiagrams illustrating the results of further processing of thesemiconductor structures whose schematic cross-sectional and plan-viewdiagrams are illustrated in FIG. 3 and FIG. 4.

FIG. 5 and FIG. 6 show: (1) a passivated dielectric layer 12′; (2) apassivated patterned hard mask layer 16′; (3) a pair of passivated gatedielectric layers 18 a′ and 18 b′; and (4) a passivated patternedcapping layer 22′ that are formed, respectively, from: (1) thedielectric layer 12, (2) the patterned hard mask layer 16; (3) the pairof gate dielectric layers 18 a and 18 b; and (4) the patterned cappinglayer 22 that are illustrated in FIG. 3 and FIG. 4. Within the contextof the instant embodiment, passivating each of the foregoing layers toprovide each of the corresponding foregoing passivated layers isintended to include a treatment or modification of each of the layers.The treatment or modification provides each of the exposed surfaces ofeach of the resulting passivated layers with a considerably decreasedsensitivity for forming a deposited material layer thereupon while usinga particular vapor deposition method. Particular types of materiallayers that may be deposited, and particular types of vapor depositionmethods that may be used for depositing the particular types of materiallayers, are disclosed in further detail below.

Within the instant embodiment, passivation is effected by treating: (1)the exposed top surface of the dielectric layer 12; (2) the exposed topand sidewall surfaces of the patterned hard mask layer 16; (3) theexposed sidewall surfaces of the pair of gate dielectric layers 18 a and18 b; and (4) the exposed top and sidewall surfaces of the patternedcapping layer 22, so that the indicated surfaces of the foregoing layers12, 16, 18 a and 18 b, and 22 (when treated) do not have a chemicalfunctionality that promotes formation of the aforementioned materiallayer deposited by the vapor deposition method. In accord with furtherdisclosure above, such a deposition inhibiting (i.e., passivating)chemical surface is generally a non-functional organic surface (i.e., analkylated surface). The alkyl (or other non-functional organic surface)generally provides a non-wettable surface.

Within the context of a silicon oxide surface or a silicon nitridesurface that is desired to be passivated to provide an alkylatedsurface, the invention contemplates use of any of a number ofsubstituted silane materials as silicon oxide or silicon nitride surfacealkylating agents. The silane materials that are surface alkylatingagents within the context of the invention are desirably notdeactivating to a patterned mandral layer of a materials compositiondisclosed above.

Specific but not limiting examples of substituted silane surfacealkylating agents include dimethyl-bis-acetato silane,methyl-tris-acetato silane, neopentyl-tris-acetato silane,di-neopentyl-bis-acetato silane, phenyl-tris-acetato silane,di-phenyl-bis-acetato silane. Also included are analogous substitutedsilane surface alkylating agents in which an acetate (i.e., acetato)functionality is substituted with an isocyanato-, trifluoroacetato-,methylsulfonato- (or alkylsulfonato-), thiocyanato-, triflatato-, iodo-,bromo-, chloro- or related functionality.

Certain analogous phosphonato-materials may be used as alternativesurface alkylating agents.

With respect to substituted silane surface alkylating agents comprisingacetate functionality, any reaction with an anhydride polymer (such as amaleic anhydride polymer), or with serendipitous carboxylic acid groupson a patterned mandrel layer surface, would be expected to produce asecondary anhydride (or reactive silicon containing) group. A completereaction and quenching of a primary anhydride functionality to yield apassivated (i.e., unreactive) mandral layer surface is not anticipatedwithin the context of the invention.

Treatment with the foregoing surface alkylating agents may be undertakenusing any of several methods. Non-limiting examples of methods include:(1) vapor immersion methods (i.e., from about 10 to about 100 volumepercent within an inert carrier gas, and possibly at elevatedpressures); and (2) dilute (i.e., from about 5 to about 30 weightpercent) solution immersion methods and spin coating methods. Typically,a silicon oxide or silicon nitride surface is treated with a surfacealkylating agent and then thermally annealed at a temperature of about100° C. to about 200° C. to assure adequate surface reaction andfunctionalization.

FIG. 7 and FIG. 8 show a pair of schematic cross-sectional and plan-viewdiagrams illustrating the results of further processing of thesemiconductor structure whose schematic cross-sectional and plan-viewdiagrams are illustrated in FIG. 5 and FIG. 6.

In particular, FIG. 7 shows an activated patterned mandrel layer 20′that results from activating the patterned mandrel layer 20 that isillustrated in FIG. 5. The activated patterned mandrel layer 20′ isotherwise located aligned beneath the passivated patterned capping layer22′ that is illustrated in FIG. 8.

Activation of the patterned mandrel layer 20 to provide the activatedpatterned mandrel layer 20′ is undertaken within the context of thedisclosure above. Activation of the patterned mandrel layer 20 toprovide the activated patterned mandrel layer 20′ provides the activatedpatterned mandrel layer 20′ with a chemical functionality that providesa wettable surface that promotes deposition of a material layerthereupon while using a vapor deposition method. In accordance withdisclosure above, desirable chemical functionality to provide such anactivated surface is generally an organic acid, alcohol or aminefunctionality.

Within the context of the instant embodiment, an amine activatingsurface functionality for the activated patterned mandrel layer 20′ maybe effected by surface reaction of a multifunctional amine with thepolymerized maleic anhydride material from which is preferably comprisedthe patterned mandrel layer 20. Suitable multifunctional amines mayinclude, but are not limited to: ethylene diamine, ethylene triamine andother alkyl multiamines, as well as polyamidoamine dendrimers (availablefrom Aldrich Chemical as Starburst Dendrimer™ comprising a 10% w/vsolution in methanol). Such a suitable amine may be surface reacted withthe preferred polymerized maleic anhydride material from which iscomprised the patterned mandrel layer 20 while using any of severalmethods. The methods may include, but are not limited to: thermallyactivated vapor phase treatment methods, spin coating methods andsolution treatment methods. Solution treatment methods are generallypreferred. For spin coating methods and solution treatment methods,typical concentrations of multifunctional amine range from about 5 toabout 30 weight percent in a polar solvent. The polar solvent may be anaqueous based solvent, an alcohol based solvent (e.g., methanol,ethanol, propanol or higher alcohol) or any other polar solvent thatdoes not detrimentally affect the mandrel material, but in which anappropriate amine is soluble. Surface treatment times may range fromabout 1 to about 20 minutes. Post-treatment curing temperatures rangingfrom about 100° to about 125° C. are common. A post-treatment solventrinse may be desirable to remove excess amine from a treated surface,and to enhance selectivity.

FIG. 9 and FIG. 10 show a pair of schematic cross-sectional andplan-view diagrams illustrating the results of further processing of thesemiconductor structure whose schematic cross-sectional and plan-viewdiagrams are illustrated in FIG. 7 and FIG. 8.

FIG. 9 and FIG. 10 show a pair of laterally grown first spacer materiallayers 24 a and 24 b located and formed laterally adjacent (andadjoining) a pair of opposite sidewalls of the activated patternedmandrel layer 20′. The pair of laterally grown first spacer materiallayers 24 a and 24 b intrinsically do not grow: (1) upon exposedhorizontal surfaces of the passivated dielectric layer 12′; (2) nor uponthe exposed horizontal and vertical surfaces of the passivated patternedhard mask layer 16′; (3) nor upon the exposed vertical surfaces of thepassivated gate dielectric layers 18 a′ and 18 b′; (4) nor upon theexposed sidewall or top surfaces of the passivated patterned cappinglayer 22′. Rather the pair of laterally grown first spacer materiallayers 24 a and 24 b grow laterally away from the activated patternedmandrel layer 20′ vertical surfaces only. As a result of this lateralgrowth, portions of the laterally grown first spacer material layers 24a and 24 b cover portions of the passivated dielectric layer 12′, thepassivated patterned hard mask layer 16′ and the passivated gatedielectric layers 18 a′ and 18 b′ upon which they would otherwise notgrow.

The pair of laterally grown first spacer material layers 24 a and 24 bmany comprise any of several spacer materials. Non-limiting examples ofspacer materials include conductor, semiconductor and dielectric spacermaterials. Semiconductor spacer materials are not particularly commonwithin the context of the instant embodiment, but they are nonethelessalso not excluded. Rather, both dielectric spacer materials andconductor spacer materials are both more desirable and more common.Dielectric spacer materials may comprise oxide, nitride or oxynitridedielectric spacer materials, although other dielectric spacer materialsare not excluded. Oxide spacer materials are common. Conductor spacermaterials may comprise certain metals or metal alloys, but are morelikely to include certain metal silicides and certain metal nitrides.Other conductor spacer materials are also not excluded.

Particular examples of deposition methods for dielectric spacermaterials, including silicon oxide, are taught within Gordon et al., inU.S. Publication No. 2004/0043149. In particular for silicon oxidematerials, an atomic layer deposition method may be undertaken by usingalternating doses of tetraisocyanatosilane and tris(tert-butoxy)silanol.As a preferred alternative, an appropriate substrate (such as apreferred amine treated maleic anhydride patterned mandral layersubstrate) may be first treated with a trimethyl aluminum activant,followed by deposition of a silicon oxide material while using a singlecycle deposition method that uses a tris(tert-butoxy)silanol startingmaterial. A deposition temperature of 200-250° C. is preferred, with200-225° C. more preferred. The use of a single cycle deposition methodis desirable since such a process has enhanced selectivity and a reducedopportunity for nucleation is undesired areas. Deposition pressures fromabout 0.1 to about 1.0 torr are common. Flow rates from about 1 e-10 to1 e-8 moles of active reactant per square centimeter surface area arealso common. Individual reactant cycle times from about 2 to about 10seconds are similarly also common.

Metal nitride layers and metal silicide layers may be deposited whileusing related deposition conditions and limitations. McElwee-White etal. in U.S. Pub. No. 2002/0045343 in particular teach the use of singleimido tungsten imido precursors (i.e., W(NR)(X)y(L)5−y) for formingtungsten nitride layers while using a metal-organic chemical vapordeposition method. The precursors are hexa-coordinate, and the fiveremaining ligands X and L may comprise several chemical moieties otherthan imido moieties. Cabral Jr, et al., in U.S. Pat. No. 6,943,097 teachthe use of: (1) group IVB (i.e., titanium, zirconium or hafnium) and VB(i.e., vanadium, niobium or tantalum) metal halides; (2) silanes of oneto ten silicon atoms; and (3) optionally activated nitrogen materials,as source materials for forming conductor metal silicides and conductormetal silicide nitrides while using an atomic layer deposition method.

Atomic layer deposition methods may also be used for depositing layerscomprising metals such as copper, nickel or platinum. Depositionconditions similar to those cited above may be used. The layers mayoften be deposited using acetylacetonate coordination complexes of theappropriate metals.

Typically, the pair of laterally grown first spacer material layers 24 aand 24 b comprises a silicon oxide material or other dielectricmaterial. Each of the pair of laterally grown first spacer materiallayers 24 a and 24 b has a thickness from about 50 to about 200angstroms. Each of the pair of laterally grown first spacer materiallayers 24 a and 24 b may be formed using any of several vapor depositionmethods beyond the specific method outlined above. Non-limiting examplesinclude physical vapor deposition methods as well as chemical vapordeposition methods that may include, but are not limited to, atomiclayer deposition methods.

FIG. 11 and FIG. 12 show a pair of schematic cross-sectional andplan-view diagrams illustrating the results of further processing of thesemiconductor structures whose schematic cross-sectional and plan-viewdiagrams are illustrated in FIG. 9 and FIG. 10.

FIG. 11 and FIG. 12 show a pair of laterally grown gate electrodes 26 aand 26 b located laterally adjacent (and adjoining) the pair oflaterally grown first spacer material layers 24 a and 24 b.

The pair of laterally grown gate electrodes 26 a and 26 b is formed of aconductor material. Exemplary but not limiting conductor materialsinclude platinum, tantalum, and in particular tantalum nitride,conductor materials. Other nitride conductor materials and relatedalternative silicide conductor materials are common and are alsodisclosed in greater detail above. Typically each of the pair oflaterally grown gate electrodes 26 a and 26 b comprises a metal nitride,preferably tantalum nitride, gate electrode material that has alinewidth from about 200 to about 500 angstroms.

In order to efficiently grow the pair of laterally grown gate electrodes26 a and 26 b laterally upon the pair of laterally grown first spacermaterial layers 24 a and 24 b, an additional activation of the pair oflaterally grown first spacer material layers 24 a and 24 b is oftendesirable. Such an additional activation of the pair of laterally grownfirst spacer material layers 24 a and 24 b may be effected by treatmentthereof with an alkyl aluminum activant followed by subsequent treatmentthereof with ammonia to again provide an amine rich surface. Other alkylmetal activants may also be used. Particular alkyl aluminum activantsmay include, but are not limited to: trimethyl aluminum, triethylaluminum and tributyl aluminum. Activation of the pair of laterallygrown first spacer material layers 24 a and 24 b with the alkyl aluminumactivant may be effected using any of several methods. Non-limitingexamples include vapor immersion methods and solution immersion methods.Vapor immersion activation is preferred, and it may be effected at aboutroom temperature and room pressure while using an alkyl aluminumactivant concentration from about 0.1 to about 3 volume percent in aninert carrier gas flow from about 100 to about 1000 standard cubiccentimeters per minute. Subsequent ammonia treatment and nitrogenationmay also be effected using several methods, but gas phase treatment ispreferred for this process step also.

Ammonia gas treatment may be undertaken at room temperature and roompressure with a pure ammonia gas flow rate from about 1 to about 10cubic centimeters per minute.

FIG. 13 and FIG. 14 show a pair of schematic cross-sectional andplan-view diagrams illustrating the results of further processing of thesemiconductor structure whose schematic cross-sectional and plan-viewdiagrams are illustrated in FIG. 11 and FIG. 12.

FIG. 13 and FIG. 14 further illustrate a pair of laterally grown secondspacer material layers 28 a and 28 b located laterally adjacent (andadjoining) the pair of laterally grown gate electrodes 26 a and 26 b.

The pair of laterally grown second spacer material layers 28 a and 28 bis laterally grown using the same methodology and materials that areused when growing the pair of laterally grown first spacer materiallayers 24 a and 24 b. The pair of laterally grown second spacer materiallayers 28 a and 28 b is grown upon the pair of laterally grown gateelectrodes 26 a and 26 b. The pair of laterally grown gate electrodes 26a and 26 b preferably comprises a conductor nitride material, such as atantalum nitride material deposited using an atomic layer depositionmethod. For example, the atomic layer deposition method may use an imidotantalum or tantalum amide source material, either by itself or inconjunction with an ammonia nitrogen source material. Under certaincircumstances, the pair of laterally grown gate electrodes 26 a and 26 bmay be activated while using only a metal alkyl treatment as disclosedabove, since an ammonia reactant comprises a part of the laterally growngate electrode 26 a and 26 b deposition process. Preferably, each of thelaterally grown second spacer material layers 28 a and 28 b comprises asilicon oxide material having a lateral thickness from about 50 to about200 angstroms and deposited using a vapor deposition method, such as inparticular a atomic layer deposition method.

FIG. 15 and FIG. 16 show a pair of schematic cross-sectional andplan-view diagrams illustrating the results of further processing of thesemiconductor structure whose schematic cross-sectional and plan-viewdiagrams are illustrated in FIG. 13 and FIG. 14.

FIG. 15 and FIG. 16 show a patterned photoresist layer 30 located upon acentral portion of the passivated patterned capping layer 22′ (andactivated patterned mandrel layer 20′ aligned therebeneath), the pair oflaterally grown first spacer material layers 24 a and 24 b, the pair oflaterally grown gate electrodes 26 a and 26 b and the pair of laterallygrown second spacer material layers 28 a and 28 b. End portions of theforegoing capping layer, spacer layers and gate electrodes are leftexposed by the patterned photoresist layer 30 so that they may befurther processed in accordance with the instant embodiment.

The patterned photoresist layer 30 may comprise any of severalphotoresist materials that are conventional in the semiconductorfabrication art. Non-limiting examples include positive photoresistmaterials, negative photoresist materials and hybrid photoresistmaterials. Typically, the patterned photoresist layer has a thicknessfrom about 5000 to about 10000 angstroms so that it may optimally covera complete thickness of all features and layers that it is required tocover. The patterned photoresist layer 30 is typically formed usingconventional photoresist processing methods and apparatus. The methodsand apparatus may include, but are not limited to spin coating,photoexposure and development methods and apparatus that areconventional in the semiconductor fabrication art.

FIG. 17 and FIG. 18 show a pair of schematic cross-sectional andplan-view diagrams illustrating the results of further processing of thesemiconductor structure whose schematic cross-sectional and plan-viewdiagrams are illustrated in FIG. 15 and FIG. 16.

FIG. 17 and FIG. 18 show a pair of patterned first spacer layers 24 a′and 24 b′, a pair of patterned gate electrodes 26 a′ and 26 b′ and apair of patterned second spacer layers 28 a′ and 28 b′. The foregoingpatterned spacer layers and patterned gate electrodes are formedincident to patterning of the corresponding laterally grown first spacermaterial layers 24 a and 24 b, the laterally grown gate electrodes 26 aand 26 b and the laterally grown second spacer material layers 28 a and28 b. The patterning is effected while using the patterned photoresistlayer 30 as illustrated in FIG. 15 and FIG. 16 as a mask, along withparticular etch methods that are conventional in the semiconductorfabrication art. The etch methods may include, but are not limited to,dry plasma etch methods and wet chemical etch methods. Under certaincircumstances, fluorine containing etchant gas compositions may be usedto etch both silicon oxide materials and tantalum nitride conductormaterials although the embodiment is not limited to use of only a singleetchant gas or a single plasma etch method.

Subsequent to patterning of the pair of laterally grown first spacermaterial layers 24 a and 24 b, the pair of laterally grown gateelectrodes 26 a and 26 b and the pair of laterally grown second spacermaterial layers 28 a and 28 b, each of the patterned photoresist layer30, the passivated patterned capping layer 22′ and the passivatedpatterned mandrel layer 20′ and exposed portions of the passivatedpatterned hard mask layer 16′ is stripped from the semiconductorstructure that is illustrated in FIG. 15 and FIG. 16 to provide in partthe semiconductor structures that are illustrated in FIG. 17 and FIG.18. The foregoing layers may be stripped while using methods andmaterials that are conventional in the semiconductor fabrication art. Anappropriate photoresist stripping material may be used to strip thepatterned photoresist layer 30. The passivated patterned capping layer22′ and exposed portions of the passivated patterned hard mask layer 16′may be stripped while using a plasma stripping method. Residual sectionsof a doubly patterned hard mask layer 16″ remain interposed between thepatterned gate electrodes 26 a′ and 26 b′, and the semiconductor fin 14.Other etchants may also be used. The activated patterned mandrel layer20′ may typically be stripped while using a solvent stripping method oran oxygen plasma stripping method. As a result of the foregoingstripping treatments, the passivated dielectric layer 12′ and thepassivated gate dielectric layers 18 a′ and 18 b′ may be returned to anunpassivated state, as illustrated in FIG. 17 and FIG. 18.

FIG. 17 and FIG. 18 show a pair of schematic cross-sectional andplan-view diagrams illustrating a finFET structure in accordance withthe preferred embodiment of the invention. The finFET structurecomprises a semiconductor fin 14 located upon a substrate 12 and havinga pair of gate dielectric layers 18 a and 18 b located upon a pair ofopposite sidewalls of the semiconductor fin 14. The finFET structurefurther comprises, for example, a laterally grown patterned gateelectrode 26 a′ that traverses the semiconductor fin 14 and the pair ofgate dielectric layers 18 a and 18 b. Finally, the finFET structure alsocomprises a pair of spacer layers (i.e., patterned first spacer layer 24a′ and patterned second spacer layer 28 a′) located and formed adjacentthe laterally grown patterned gate electrode 26 a′. The foregoing pairof spacer layers is located completely covering a sidewall of thepatterned gate electrode 26 a′, but not completely covering a sidewallof the semiconductor fin 14 remote from the laterally grown patternedgate electrode 26 a′.

The finFET structure of FIG. 17 and FIG. 18 uses a laterally specific(i.e., sidewall specific) vapor deposition method for forming the pairof patterned first spacer layers 24 a′ and 24 b′, the pair of patternedgate electrodes 26 a′ and 26 b′, and the pair of patterned second spacerlayers 28 a′ and 28 b′. By using such a method, each of the patternedfirst spacer layers 24 a′ and 24 b′, the patterned gate electrodes 26 a′and 26 b′ and the patterned second spacer layers 28 a′ and 28 b′ may beformed with a linewidth less than a minimum photo resolvable linewidth.In addition, by using the laterally specific deposition method, thepatterned gate electrodes 26 a′ and 26 b′ are formed absent aphotolithographic method that requires photo registration over layersand structures having substantial topography. Thus, a finFET structurein accordance with the preferred embodiment of the invention isfabricated with enhanced manufacturability.

Although the preferred embodiment of the invention illustrates theinvention within the context of forming a spacer clad gate electrode fora finFET device, the invention is not intended to be so limited. Ratherin a most general sense, the invention provides a method for forminglaterally grown structures of several varieties within a microelectronicstructure that is typically a semiconductor structure. Laterally grownstructures that may be formed using the method include, but are notlimited to: conductor structures, semiconductor structures anddielectric structures.

The preferred embodiment of the invention is illustrative of theinvention rather than limiting of the invention. Revisions andmodifications may be made to methods, materials, structures anddimensions of a finFET structure and methods for fabrication thereof inaccordance with the preferred embodiment of the invention, while stillproviding a structure and methods for fabrication thereof in accordancewith the invention, further in accordance with the accompanying claims.

What is claimed is:
 1. A method for fabricating a structure comprising:forming a mandrel layer over a substrate, where a sidewall of themandrel layer is activated with respect to vapor deposition of amaterial layer upon the sidewall of the mandrel layer while a surface ofthe substrate is passivated with respect to vapor deposition of thematerial layer upon the surface of the substrate; and vapor depositingand selectively laterally growing the material layer upon the sidewallof the mandrel layer but not upon the surface of the substrate.
 2. Themethod of claim 1 wherein the step of forming the mandrel layer over thesubstrate comprises forming the mandrel layer that comprises a maleicanhydride material over the substrate.
 3. The method of claim 1 whereinthe step of forming the mandrel layer over the substrate, where thesidewall of the mandrel layer is activated with respect to vapordeposition of a material layer upon the sidewall of the mandrel layercomprises forming the mandrel layer over the substrate, where thesidewall of the mandrel layer is activated with respect to vapordeposition of a material layer upon the sidewall of the mandrel layer byusing at least one of an organic acid, hydroxyl and amine activant. 4.The method of claim 1 wherein the step of forming the mandrel layer overthe substrate comprises forming the mandrel layer over the substratethat comprises a silicon oxide surface.
 5. The method of claim 1 whereinthe step of forming the mandrel layer over the substrate, where thesurface of the substrate is passivated with respect to vapor depositionof a material layer upon the surface of the substrate comprises formingthe mandrel layer over the substrate, where the surface of the substrateis passivated with respect to vapor deposition of a material layer uponthe surface of the substrate by using a substituted silane passivant. 6.The method of claim 1 wherein the step of vapor depositing andselectively laterally growing the material layer upon the sidewall ofthe mandrel layer but not upon the surface of the substrate comprisesvapor depositing and selectively laterally growing the material layerthat comprises a dielectric material upon the sidewall of the mandrellayer but not upon the surface of the substrate.
 7. The method of claim1 wherein the step of vapor depositing and selectively laterally growingthe material layer upon the sidewall of the mandrel layer but not uponthe surface of the substrate comprises vapor depositing and selectivelylaterally growing the material layer that comprises a conductor materialupon the sidewall of the mandrel layer but not upon the surface of thesubstrate.
 8. The method of claim 1 wherein the step of vapor depositingand selectively laterally growing the material layer upon the sidewallof the mandrel layer but not upon the surface of the substrate comprisesvapor depositing and selectively laterally growing the material layerthat comprises a lateral laminate of a dielectric material and aconductor material upon the sidewall of the mandrel layer but not uponthe surface of the substrate.
 9. The method of claim 1 wherein the stepof vapor depositing and selectively laterally growing the material layerupon the sidewall of the mandrel layer but not upon the surface of thesubstrate comprises vapor depositing and selectively laterally growingthe material layer that comprises a gate electrode upon the sidewall ofthe mandrel layer but not upon the surface of the substrate.
 10. Themethod of claim 1 wherein the step of vapor depositing and selectivelylaterally growing the material layer upon the sidewall of the mandrellayer but not upon the surface of the substrate comprises vapordepositing and selectively laterally growing the material layer thatcomprises a gate electrode within a finFET upon the sidewall of themandrel layer but not upon the surface of the substrate.